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合成了标题化合物丙酮溶剂化(2-氨基吡啶)(5,10,15,20-四苯基)卟啉镉(II)[Cd(TPP)(C5H6N2)]·CH3OCH3,并用X-射线衍射法测定了其晶体结构,该化合物属于三斜晶系,P-1空间群,晶胞参数为a=1.133 1(2)nm,b=1.327 5(3)nm,c=1.516 0(3)nm,Z=2,Dc=1.358 g.cm-3,μ=0.555 mm-1,F(000)=900,最终结构偏离因子R=0.038 7,Rw=0.099 8,S=1.084。通过红外光谱(IR)、紫外-可见光谱(UV-Vis)对化合物的光学性质进行了表征。
The title compound Cd (TPP) (C5H6N2)] .CH3OCH3 was synthesized by acetone solvation of 2-aminopyridine (5,10,15,20-tetraphenyl) porphyrin and was characterized by X-ray diffraction The crystal structure of the compound belongs to the triclinic system, P-1 space group with unit cell parameters of a = 1.133 1 (2) nm, b = 1.327 5 (3) nm and c = 1.516 0 , Z = 2, Dc = 1.358 g.cm-3, μ = 0.555 mm-1, F (000) = 900 and the final structure deviation factor R = 0.038 7, Rw = 0.099 8, S = 1.084. The optical properties of the compounds were characterized by infrared spectroscopy (IR) and ultraviolet-visible spectroscopy (UV-Vis).