【摘 要】
：
We report an air-stable (π-allyl)iridium complex derived from dinaphthocyclooctatetraene and a phosphoramidite ligand.It was found highly efficient in iridium-catalyzed allylic substitution reactions.
【机 构】
：
State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Aca
【出 处】
：
The 24th International Society of Heterocyclic Chemistry Con
论文部分内容阅读
We report an air-stable (π-allyl)iridium complex derived from dinaphthocyclooctatetraene and a phosphoramidite ligand.It was found highly efficient in iridium-catalyzed allylic substitution reactions.This catalyst features excellent regioselectivity and high stability.When NaCH(CO2Me)2 was used as the nucleophile, catalyst loading in allylic alkylation reactions can be as low as 0.01 mol％.
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