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Kollonitsch曾报道乙硼氢与四氢呋喃在Carius管中60℃加热64小时,生成硼酸丁酯,产率61％;若反应在室温下进行,需16周才能完成。继后,Past将φSBH_2与醚R′OR″反应,获得φSR′和H_2BOR″。Freeguard等将乙硼氢,戊硼氢-9或钠硼氢和卤素(Cl_2、Br_2、I_2、ICl)与醚类或醇类在常温下反应,醚键很快发生断裂,生成相应的卤化物和硼酸酯,产率达80％以上;二苯醚与具有β-卤素取代基的醇则不能顺利反应。Beachell等曾研究了癸硼氢与醇类的反应,获知诱导效应对癸硼氢的醇解速率有很大的影
Kollonitsch reported that borohydride and tetrahydrofuran were heated in a Carius tube at 60 ° C for 64 hours to yield butyl borate in a yield of 61%. It took 16 weeks for the reaction to proceed at room temperature. Next, Past reacts φSBH_2 with ether R’OR “to obtain φSR ’and H_2BOR”. Freeguard and other B borohydrogen, pentabromo-9 or sodium borohydride and halogen (Cl_2, Br_2, I_2, ICl) and ether or alcohol at room temperature reaction, the ether bond soon rupture to generate the corresponding halide And boric acid ester, the yield is more than 80%; diphenyl ether and β-halogen substituted alcohol can not react smoothly. Beachell et al. Studied the reaction of decabromohydrin with alcohols and found that the induction effect has a great influence on the rate of decabromohydrolysis