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In order to investigate the possibility of Si thin film as an anode for Na battery,we studied the electrochemical intercalation of sodium into the Si film.Amorphous Si thin film electrode was prepared using DC magnetron sputtering.Sodium ion could intercalate into Si thin film upto Na0.52Si,i.e.530mAh·g-1-Si.The first discharge capacity was 80mAh·g-1-Si,which meant reversible amount of sodium intercalation.The discharge capacity slightly decreased to 70mAh·g-1-Si after 10 cycles.
In order to investigate the possibility of Si thin film as an anode for Na battery, we studied the electrochemical intercalation of sodium into the Si film. A morphous Si thin film electrode was prepared using DC magnetron sputtering. Sodium ion could intercalate into Si thin film upto Na0.52Si, ie530mAh · g-1-Si. The first discharge capacity was 80mAh · g-1-Si, which indicates a reversible amount of sodium intercalation. The discharge capacity slightly decreased to 70mAh · g-1-Si after 10 cycles .