含环戊二烯络铁(CpFe)基团氯化苯类化合物受CpFe吸电子基团的影响,苯环上的氯原子很活泼,常温下就可与含-OH、-SH、-NH2等基团的有机化合物进行亲核取代反应,选择性强,收率高。文章简要介绍了含CpFe基团氯化苯类化合物的合成以及用其制备环状化合物、有机化合物、金属高分子材料和有机高分子材料的过程。 Chlorinated compounds containing cyclopentadienyl iron (CpFe) groups are affected by CpFe electron-withdrawing groups. Chlorine atoms on the benzene ring are very active and can react with -OH, -SH, -NH2 and the like at room temperature Group of organic compounds nucleophilic substitution reaction, strong selectivity, high yield. In this paper, the synthesis of chlorinated benzenes containing CpFe groups and the preparation of cyclic compounds, organic compounds, metallic polymers and organic polymeric materials are briefly introduced.